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Characterization of bitumens using high performance gel permeation - Chromotography and thermal analysis for improving performance of bitumen/polymer mlends for waterproofing

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Abstract
Four different fractions of bitumens (asphaltenes, saturates, naphthenes aromatic and polar aromatics) of differnt origins (Iran, Arabia and Mexico) were characterized by high-performance gel permeation chromatography and differential scanning calorimetry. The three different bitumens were determined to have similar penetration range and adequate chemical composition to be used for waterproofing applications. HP-GPC was used to determine the molecular weights of the various bituminous fractions. The trend in molecular weights for the fraction was, in decreasing order, asphaltene, polar aromatics; saturates and naphthten aromatics. The glass transition temperature and other thermally induced transitions were obtained by DSC. It was also found that the combination of these techniques leads to a better understanding of the properties of the bitumens and assists in developing superior polymer-modified bitumen blends for roofing and waterproofing membranes.
Date
0/1992
Author(s)
R Parol; O Dutt; I Rodriguez; M Fernandez
Page(s)
420-430
Keyword(s)
asphaltenes; saturates; naphthenes aromatic; polar aromatic; HP-GPC; gel permeation; differential scanning calorimetry; DSC


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